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Temperature dependence of AlInAs band gap energy and AlInAs/InP band offsets

Identifieur interne : 016643 ( Main/Repository ); précédent : 016642; suivant : 016644

Temperature dependence of AlInAs band gap energy and AlInAs/InP band offsets

Auteurs : RBID : Pascal:99-0024924

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Abstract

The temperature variations of the AlInAs photoluminescence (PL) transition energies and the AlInAs/InP interface staggered lineup luminescence (SLL) energy are reported. The S shape appearing from 4 to 90 K on the energy v. temperature curves of these PL energies are owing to extrinsic recombinations. In particular, the S shape of the SLL energy curve v. temperature is probably a result of acceptor impurities localised in AlInAs at the interface (on edge impurities). The band offsets were determined by solving the Schrödinger and Poisson equations with a self consistent calculation program. At 4.5 K, the conduction and valence hand offsets are 0.384 and 0.295 eV respectively. Their temperature variation is shown to be important: 35 and 23 meV at 4.5 and 300 K respectively. The Van Vechten and Malloy model (following a thermodynamic approach) for the temperature variation of the band offsets is compared to the results in the present work.

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<div type="abstract" xml:lang="en">The temperature variations of the AlInAs photoluminescence (PL) transition energies and the AlInAs/InP interface staggered lineup luminescence (SLL) energy are reported. The S shape appearing from 4 to 90 K on the energy v. temperature curves of these PL energies are owing to extrinsic recombinations. In particular, the S shape of the SLL energy curve v. temperature is probably a result of acceptor impurities localised in AlInAs at the interface (on edge impurities). The band offsets were determined by solving the Schrödinger and Poisson equations with a self consistent calculation program. At 4.5 K, the conduction and valence hand offsets are 0.384 and 0.295 eV respectively. Their temperature variation is shown to be important: 35 and 23 meV at 4.5 and 300 K respectively. The Van Vechten and Malloy model (following a thermodynamic approach) for the temperature variation of the band offsets is compared to the results in the present work.</div>
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